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Lpn. Acad. 44,352. Timberlake, C. F. (1980). Food Chern. 5, 69. Timberlake, C. , and Bridle, P. (1%5). Chern. indo (London) p. 1520. Timberlake, C. , and Bridle, P. (1966). Nature (London) 212, 158. Timberlake, C. , and Bridle, P. (1%7). l. Sci. Food Agric. 18,473. Timberlake, C. , and Bridle, P. (1%8). Chern. indo (London) p. 1489. Timberlake, C. , and Bridle, P. (1975). In "The F1avonoids" (J. B. Harborne, T. J. Mabry, and H. ), p. 214. Chapman & Hall, London. Timberlake, C. , and Bridle, P. (1980).
There are three negatively charged prototropic tautomers, ATII, AT4', and AM" and six acidity constants, K~75 = ([A T5 ]/[A7])aH+, K~7'" = ([AT4']/[A7])aH+, K~1I7 = ([AT5]/[A5])aH+,K~1I4' = ([Aw]/[AII])aH+,K~4'5 = ([Aw]/[A... ]/[A 4·])a H+' At present, the values of these six elementary Raymond Brouillard 16 ,0 ~ -=7 Scheme 3 constants are unknown. The existence of one or more of the three neutral tautomers and of one or more of the three negatively charged tautomers is shown by the large bathochromic shift that occurs in the visible spectrum of a natural anthocyanin when the pH increases from 2 to 10 (Fig.
Copigmentation ........................ . . . . . . . . . . . . . . . F. Miscellaneous........................................................ III. Copigmentation in Some Detail ........................................... A. Discovery of Copigments ............................................. B. Definition, Nature, and Mechanism of Copigmentation ................... C. Factors Affecting Copigmentation ....... " .. .. .. . .. . .. . .. D. Anticipation and Representation of Copigmentation ......................